Choosing a Grating and a Slit
| Each channel in an WPI spectrometer can be configured with one of 14 different gratings, fixed in place at the time of manufacture, that cover the UV-VIS-Shortwave NIR. The grating that yields the optimum wavelength range, optical resolution and signal for your application must be specified at the time of order.
Grating options are described in Spectrometer Grating Chart. Information on grating efficiency curves and related data is also available. Also, multiple spectrometer channels, each with its own grating, can be added to a Master channel for expanded wavelength range, multi-tasking or reference monitoring.
Users must select a grating (including starting and ending wavelengths) and optical bench accessories for each spectrometer channel. Additional grating selection guidelines appear in the footnotes below. Spectrometer system response depends on the grating and the detector. The grating efficiency ranges reported here are truncated to the response range of the CCD linear-array detector -- 200-1100 nm. Optimum system performance is between 220-1000 nm. To see the efficiency curve of a specific grating, click on the Grating # in the far left column. To compare similar gratings, click on the entry in the Lines/mm column.
|
|
|
|||||
|
|
Intended Use |
|
|
|
Efficiency > 30% |
|
|
UV |
|
|
|
200-575 nm |
|
|
UV / VIS |
|
|
|
250-800 nm |
|
|
VIS / color |
|
|
|
350-850 nm |
|
|
NIR |
|
|
|
530-1100 nm |
|
|
UV / VIS |
|
|
|
200-400 nm |
|
|
NIR |
|
|
|
500-1100 nm |
|
|
UV / VIS |
|
|
|
200-500 nm |
|
|
UV |
|
|
|
290-340 nm |
|
|
VIS/NIR |
|
|
|
400-800 nm |
|
|
UV/VIS |
|
|
|
200-635 nm |
|
|
UV/VIS |
|
|
|
320-800 nm |
|
|
UV/VIS |
|
|
|
250-575 nm* |
|
|
UV/VIS/NIR |
|
|
|
300-1100 nm |
|
|
NIR |
|
|
|
650-1100 nm |
| * The spectral range for Grating #6, #7, #9, #10, #11 and #12 will vary according to the starting wavelength range. The rule of thumb is this: the higher the starting wavelength, the lesser the spectral range. For example, the spectral range for Grating #10 is 190 nm in the UV region (<360 nm) and 100 nm in the "red" region (>600 nm).
Also, please be aware that due to optical design limitations, systems configured with Grating #12 cannot be set above ~575 nm. In fact, although the efficiency of the grating is >30% to 700 nm, the optical design of the spectrometer prevents it from "seeing" wavelengths >~575 nm. However, Grating #11 can be set at wavelengths >575 nm and <800 nm, and will achieve comparable optical resolution (FWHM). ** The spectral range for Grating #8 will vary according to the starting wavelength range. The rule of thumb is this: the higher the starting wavelength, the lesser the spectral range. *** The spectral range for Grating #13 extends beyond the response of the S2000's linear CCD-array detector (200-1100 nm). In fact, while the spectral range of a spectrometer configured with Grating #13 will span 300-2000 nm, the detector will "see" only the area from 300-1100 nm. There are two other considerations with Grating #13. First, though the grating has a very broad spectral range, it cannot be used to achieve very high resolution (<3.0 nm FWHM). Second, due to the grating's broad spectral range, second-order effects, which are characteristic of all gratings, are much more difficult to eliminate or reduce through the installation of order-sorting filters and the like. |
|||||
| SLITS | ||||||||||||
| Optical resolution -- measured as Full Width Half Maximum (FWHM) -- of a monochromatic source depends on the groove density (lines/mm) of the grating and the diameter of the entrance optics (optical fiber or slit). In configuring your spectrometer, consider two important trade-offs: 1) resolution increases with an increase in the groove density of the grating, but at the expense of spectral range and signal strength; and 2) resolution increases as the slit width or fiber diameter decreases, but at the expense of signal strength. | ||||||||||||
| The approximate optical resolution in nm (FWHM) can be calculated as follows:
1) Dispersion (nm/pixel) = Spectral Range of the Grating (see Choosing a Grating) divided by the Number of Detector Elements (2048 for S2000 or 1024 for S1024DW) 2) Resolution (in pixels) = value from slit size/fiber diameter chart 3) Optical Resolution (in nm) = Dispersion (nm/pixel value from #1) x |
||||||||||||
Typical pixel resolution by slit size/fiber diameter
|
||||||||||||
